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Novel 9,9-diol systems starting from a 3,7-diazabicyclo[3.3.1]nonan-9-one nucleus. Single crystal X-ray diffraction analysis of 3-(2-propyl)-7-benzyl-3,7-diazabicyclo[3.3.1]nonane-9,9-diol hydrobromide, 3-(2-propyl)-7-[3,4-dimethoxybenzyl)-3,7-diazabicyclo[3.3.1]nonane-9,9-diol hydrobromide, and 3,7-diisopropyl-3,7-diazabicyclo[3.3.1]nonane-9,9-diol dihydrochloride.

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